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1-(6-Fluoro-1,3-benzothia-zol-2-yl)-2-(1-phenyl-ethyl-idene)hydrazine.

ABSTRACT: The asymmetric unit of the title compound, C(15)H(12)FN(3)S, consists of two independent mol-ecules with comparable geometries. In one mol-ecule, the 1,3-benzothia-zole ring system (r.m.s. deviation = 0.011?Å) forms a dihedral angle of 19.86?(6)° with the phenyl ring. The corresponding r.m.s. deviation and dihedral angle for the other mol-ecule are 0.014?Å and 22.32?(6)°, respectively. In the crystal, mol-ecules are linked via N-H?N, C-H?F and C-H?N hydrogen bonds into a three-dimensional network. The crystal studied was a non-merohedral twin with a refined BASF value of 0.301?(2).

SUBMITTER: Fun HK 

PROVIDER: S-EPMC3414353 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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1-(6-Fluoro-1,3-benzothia-zol-2-yl)-2-(1-phenyl-ethyl-idene)hydrazine.

Fun Hoong-Kun HK   Quah Ching Kheng CK   Munirajasekhar D D   Himaja M M   Sarojini B K BK  

Acta crystallographica. Section E, Structure reports online 20120714 Pt 8

The asymmetric unit of the title compound, C(15)H(12)FN(3)S, consists of two independent mol-ecules with comparable geometries. In one mol-ecule, the 1,3-benzothia-zole ring system (r.m.s. deviation = 0.011 Å) forms a dihedral angle of 19.86 (6)° with the phenyl ring. The corresponding r.m.s. deviation and dihedral angle for the other mol-ecule are 0.014 Å and 22.32 (6)°, respectively. In the crystal, mol-ecules are linked via N-H⋯N, C-H⋯F and C-H⋯N hydrogen bonds into a three-dimensional networ  ...[more]

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