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2,5-Dichloro-N-(3-methyl-phen-yl)benzenesulfonamide.

ABSTRACT: In the title compound, C(13)H(11)Cl(2)NO(2)S, the dihedral angle between the aromatic rings is 76.62 (10)° and the C-S-N-C linkage between the rings adopts a gauche conformation [torsion angle = -51.4 (2)°]. A weak intra-molecular C-H⋯O inter-action closes an S(6) ring. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R(2) (2)(8) loops.

SUBMITTER: Mughal SY

PROVIDER: S-EPMC3414931 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Project description:The asymmetric unit of the title compound, C(14)H(13)Cl(2)NO(2)S, contains three independent moleules. The torsion angles of the C-SO2-NH-C segments in the three mol-ecules are 67.5?(2), 83.4?(2) and -77.5?(2)°. The two aromatic rings are tilted relative to each other by 68.8?(1), 64.1?(1) and 68.5?(1)°. The crystal structure features dimers linked by pairs of N-H?O hydrogen bonds.

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Project description:In the title compound, C(13)H(11)Cl(2)NO(3)S, the dihedral angle between the benzene rings is 74.37?(3)°. In the crystal, inter-molecular N-H?O hydrogen bonds link the mol-ecules into chains along the b axis.

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Project description:In the title compound, C(14)H(13)Cl(2)NO(2)S, the dihedral angle between the aromatic rings is 62.21?(7)° and the C-S-N-C group adopts a gauche conformation [torsion angle = 60.22?(17)°]. In the crystal, N-H?O hydrogen bonds link the mol-ecules into C(4) chains propagating in [010]. A short inter-molecular Cl?O contact of 3.1115?(17)?Å is seen.

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