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(R,E)-3-(4-Chloro-phen-yl)-1-phenyl-allyl 4-nitro-benzoate.

ABSTRACT: The title compound, C(22)H(16)ClNO(4), adopts a conformation in which the phenyl ring plane forms similar dihedral angles with the nitro-benzoate C(6) ring [76.97 (8)°] and the chloro-phenyl group [76.95 (8)°]; the dihedral angle between the chloro-phenyl and nitro-benzoate rings is 66.43 (8)°. In the crystal, π-π stacking is observed between the latter two planes, with a dihedral angle of 1.79 (8)° and a centroid-centroid distance of 3.735 (1) Å. In addition, mol-ecules are linked along [100] by weak C-H⋯O contacts.

SUBMITTER: Troshin K

PROVIDER: S-EPMC3414994 | biostudies-literature |

REPOSITORIES: biostudies-literature

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1-(4-Nitro-phen-yl)-2-(3-phenyl-allyl-idene)hydrazine.

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Crystal structures of 4-chloro-phenyl N-(3,5-di-nitro-phen-yl)carbamate and phenyl N-(3,5-di-nitro-phen-yl)carbamate.

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2,6-Dichloro-phen-yl 4-chloro-benzoate.

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Project description:The aromatic rings in the title compound, C13H8ClNO4, enclose a dihedral angle of 39.53?(3)°. The nitro group is almost coplanar with the ring to which it is attached [dihedral angle = 4.31?(1)°]. In the crystal, mol-ecules are connected by C-H?O hydrogen bonds into chains running along [001].

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