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1,2,3,4,5,6-Hexa-O-acetyl-scyllo-inositol.

ABSTRACT: The title mol-ecule, C(18)H(24)O(12), has crystallographic 2/m symmetry with two acetate group located on a mirror plane. The H-Csp(3)-O-Csp(2) torsion angles characterizing orientation of the acetyl groups with respect to the cyclo-hexane ring are 0.0, 23.9 and -23.9°. The cyclo-hexane ring is in a chair conformation with all substituents in equatorial positions. In the crystal, mol-ecules are connected through C-H?O hydrogen bonds into a chain extending along the c axis.

SUBMITTER: Kant R

PROVIDER: S-EPMC3415030 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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1,2,3,4,5,6-Hexa-O-acetyl-scyllo-inositol.

Kant Rajni R Gupta Vivek K VK Kapoor Kamini K Chib Renu R Shah Bhahwal A BA Taneja Subhash C SC

Acta crystallographica. Section E, Structure reports online 20120728 Pt 8

The title mol-ecule, C(18)H(24)O(12), has crystallographic 2/m symmetry with two acetate group located on a mirror plane. The H-Csp(3)-O-Csp(2) torsion angles characterizing orientation of the acetyl groups with respect to the cyclo-hexane ring are 0.0, 23.9 and -23.9°. The cyclo-hexane ring is in a chair conformation with all substituents in equatorial positions. In the crystal, mol-ecules are connected through C-H⋯O hydrogen bonds into a chain extending along the c axis. ...[more]

PMID: 22905017

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