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Rhodium(III)-catalyzed oxidative carbonylation of benzamides with carbon monoxide.

ABSTRACT: An efficient strategy for the oxidative carbonylation of aromatic amides via C-H/N-H activation to form phthalimides using an Rh(III) catalyst has been developed. The reaction shows a preference for C-H bonds of electron-rich aromatic amides and tolerates a variety of functional groups.

SUBMITTER: Du Y

PROVIDER: S-EPMC3423973 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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Rhodium(III)-catalyzed oxidative carbonylation of benzamides with carbon monoxide.

Du Ya Y Hyster Todd K TK Rovis Tomislav T

Chemical communications (Cambridge, England) 20111017 44

An efficient strategy for the oxidative carbonylation of aromatic amides via C-H/N-H activation to form phthalimides using an Rh(III) catalyst has been developed. The reaction shows a preference for C-H bonds of electron-rich aromatic amides and tolerates a variety of functional groups. ...[more]

PMID: 22006288

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