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Dimorpholinium tetra-chlorido-cobaltate(II).

ABSTRACT: In the title mol-ecular salt, (C(4)H(10)NO)(2)[CoCl(4)], the morpholinium cations adopt chair conformations and the tetra-chloridocobaltate(II) anion is significantly distorted from regular tetra-hedral geometry [Cl-Co-Cl = 102.183?(19)-117.59?(2)°]. The Co-Cl bond lengths for the chloride ions not accepting hydrogen bonds are significantly shorter than those for the chloride ions accepting such bonds. In the crystal, the components are linked by N-H?O and N-H?Cl and bifurcated N-H?(O,Cl) hydrogen bonds to generate (100) sheets.

SUBMITTER: Cao XX

PROVIDER: S-EPMC3435614 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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Dimorpholinium tetra-chlorido-cobaltate(II).

Cao Xing-Xing XX Cheng He-Long HL Feng Qing-Liu QL Chen Li-Zhuang LZ

Acta crystallographica. Section E, Structure reports online 20120823 Pt 9

In the title mol-ecular salt, (C(4)H(10)NO)(2)[CoCl(4)], the morpholinium cations adopt chair conformations and the tetra-chloridocobaltate(II) anion is significantly distorted from regular tetra-hedral geometry [Cl-Co-Cl = 102.183 (19)-117.59 (2)°]. The Co-Cl bond lengths for the chloride ions not accepting hydrogen bonds are significantly shorter than those for the chloride ions accepting such bonds. In the crystal, the components are linked by N-H⋯O and N-H⋯Cl and bifurcated N-H⋯(O,Cl) hydrog ...[more]

PMID: 22969487

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