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2-Methyl-3-nitro-N-{(E)-[5-(4-nitro-phen-yl)furan-2-yl]methyl-idene}aniline.


ABSTRACT: In the title Schiff-base type compound, C(18)H(13)N(3)O(5), the central furan ring makes dihedral angles of 12.80?(7) and 51.43?(4)° with the terminal benzene rings. The dihedral angle between the benzene rings is 45.43?(3)°. In the crystal, C-H?O hydrogen bonds link the mol-ecules into layers parallel to (010). In addition, there are ?-? stacking inter-actions within the layer [centroid-centroid distance = 3.584?(1)?Å] and between the layers [centroid-centroid distance 3.751?(1)?Å].

SUBMITTER: Pekdemir M 

PROVIDER: S-EPMC3435658 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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2-Methyl-3-nitro-N-{(E)-[5-(4-nitro-phen-yl)furan-2-yl]methyl-idene}aniline.

Pekdemir Merve M   Işık Samil S   Gümüş Sümeyye S   Ağar Erbil E   Oztürk Yıldırım Sema S   Butcher Ray J RJ  

Acta crystallographica. Section E, Structure reports online 20120804 Pt 9


In the title Schiff-base type compound, C(18)H(13)N(3)O(5), the central furan ring makes dihedral angles of 12.80 (7) and 51.43 (4)° with the terminal benzene rings. The dihedral angle between the benzene rings is 45.43 (3)°. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules into layers parallel to (010). In addition, there are π-π stacking inter-actions within the layer [centroid-centroid distance = 3.584 (1) Å] and between the layers [centroid-centroid distance 3.751 (1) Å]. ...[more]

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