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2-(4-Fluoro-phen-yl)-1-phenyl-1H-benzimidazole.

ABSTRACT: In the title mol-ecule, C(19)H(13)FN(2), the benzimidazole unit is close to planar [maximum deviation = 0.0342?(9)?Å] and forms dihedral angles of 58.94?(3) and 51.43?(3)° with the phenyl and fluoro-benzene rings, respectively; the dihedral angle between the phenyl and fluoro-benzene rings is 60.17?(6)°. In the crystal, three C-H?F hydrogen bonds and two weak C-H?? inter-actions involving the fused benzene ring lead to a three-dimensional architecture.

SUBMITTER: Jayamoorthy K

PROVIDER: S-EPMC3435725 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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2-(4-Fluoro-phen-yl)-1-phenyl-1H-benzimidazole.

Jayamoorthy K K Rosepriya S S Thiruvalluvar A A Jayabharathi J J Butcher R J RJ

Acta crystallographica. Section E, Structure reports online 20120815 Pt 9

In the title mol-ecule, C(19)H(13)FN(2), the benzimidazole unit is close to planar [maximum deviation = 0.0342 (9) Å] and forms dihedral angles of 58.94 (3) and 51.43 (3)° with the phenyl and fluoro-benzene rings, respectively; the dihedral angle between the phenyl and fluoro-benzene rings is 60.17 (6)°. In the crystal, three C-H⋯F hydrogen bonds and two weak C-H⋯π inter-actions involving the fused benzene ring lead to a three-dimensional architecture. ...[more]

PMID: 22969596

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