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The crystal structure of the Dess-Martin periodinane.

ABSTRACT: We report the elusive X-ray structure of the Dess-Martin periodinane (DMP), a hypervalent iodine reagent popular amongst synthetic chemists. In the solid state, the highly crystalline compound forms an intricate coordination polymer held together by intermolecular halogen and hydrogen bonds.

SUBMITTER: Schrockeneder A

PROVIDER: S-EPMC3458777 | biostudies-literature | 2012

REPOSITORIES: biostudies-literature

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The crystal structure of the Dess-Martin periodinane.

Schröckeneder Albert A Stichnoth Desiree D Mayer Peter P Trauner Dirk D

Beilstein journal of organic chemistry 20120912

We report the elusive X-ray structure of the Dess-Martin periodinane (DMP), a hypervalent iodine reagent popular amongst synthetic chemists. In the solid state, the highly crystalline compound forms an intricate coordination polymer held together by intermolecular halogen and hydrogen bonds. ...[more]

PMID: 23019487

Dataset Information

The crystal structure of the Dess-Martin periodinane.

Publications

The crystal structure of the Dess-Martin periodinane.

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