Ontology highlight
ABSTRACT:
SUBMITTER: Olsen MT
PROVIDER: S-EPMC3465568 | biostudies-literature | 2011 Jun
REPOSITORIES: biostudies-literature
Olsen Matthew T MT Gray Danielle L DL Rauchfuss Thomas B TB De Gioia Luca L Zampella Giuseppe G
Chemical communications (Cambridge, England) 20110601 23
Experimental and computational experiments show that the electrophile MeS(+) attacks a single Fe center in Fe(2)(propanedithiolate)(CO)(4)(PMe(3))(2) followed by isomerization of this terminal thiolato complex to the corresponding μ-SMe derivative. ...[more]