Unknown

Dataset Information

0

Catena-Poly[[[iodidocopper(I)]-{?-N-[(pyridin-2-yl-?N)methyl-idene]pyridin-3-amine-?(2)N(3):N(1)}] acetonitrile hemisolvate].

ABSTRACT: In the asymmetric unit of the title polymeric complex, {[CuI(C(11)H(9)N(3))]·0.5CH(3)CN}(n), there are two Cu(I) atoms, two N-[(pyridin-2-yl-?N)methyl-idene]pyridin-3-amine (PyPy) ligands and two I atoms. Both Cu(I) atoms have a distorted tetra-hedral geometry, each being coordinated by one I atom, two N atoms of one PyPy ligand and one N atom from an adjacent PyPy ligand. In the crystal, infinite helical chains of [Cu(2)(PyPy)(2)](n) are formed propagating along the b axis. These chains are linked via weak C-H?I hydrogen bonds and ?-? stacking inter-actions [shortest centroid-centroid distance = 3.2727?(14)?Å]. During the refinement, electron-density peaks were located that were believed to be highly disordered solvent mol-ecules (possibly acetonitrile). The SQUEEZE option in PLATON [Spek (2009 ?). Acta Cryst. D65, 148-155] indicated there were solvent cavities with a total volume of 196?Å(3) containing approximately 60 electrons per unit cell, which equated to one mol-ecule of acetonitrile per asymmetric unit.

SUBMITTER: Mahmoudi A 

PROVIDER: S-EPMC3470156 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[[iodidocopper(I)]-{μ-N-[(pyridin-2-yl-κN)methyl-idene]pyridin-3-amine-κ(2)N(3):N(1)}] acetonitrile hemisolvate].

Mahmoudi Ali A   Dehghanpour Saeed S   Babakhodaverdi Mojtaba M  

Acta crystallographica. Section E, Structure reports online 20120919 Pt 10

In the asymmetric unit of the title polymeric complex, {[CuI(C(11)H(9)N(3))]·0.5CH(3)CN}(n), there are two Cu(I) atoms, two N-[(pyridin-2-yl-κN)methyl-idene]pyridin-3-amine (PyPy) ligands and two I atoms. Both Cu(I) atoms have a distorted tetra-hedral geometry, each being coordinated by one I atom, two N atoms of one PyPy ligand and one N atom from an adjacent PyPy ligand. In the crystal, infinite helical chains of [Cu(2)(PyPy)(2)](n) are formed propagating along the b axis. These chains are lin  ...[more]

Similar Datasets

Unknown Poly[[[?3-(E)-N-(pyridin-4-yl-methyl-idene)hy-droxy-laminato-?(3) O:N:N'][?2-(E)-N-(pyridin-4-yl-methyl-idene)hydroxyl-amine-?(2) N:N'][(E)-N-(pyridin-4-yl-methyl-idene-?N)hydroxyl-amine]-disilver(I)] nitrate].
| S-EPMC3588782 | biostudies-literature
Unknown catena-Poly[[dichloridomercury(II)]-?-{N-[(E)-pyridin-2-yl-methyl-idene-?N]pyridin-3-amine-?(2)N(1):N(3)}].
| S-EPMC3470133 | biostudies-other
Unknown [(E)-Oxido(pyridin-2-yl-methyl-idene)amine-?(2)N,N'][(E)-N-(pyridin-2-yl-methyl-idene)hydroxyl-amine-?(2)N,N']silver(I) perchlorate-bis-[(E)-N-(pyridin-2-yl-methyl-idene)hydroxyl-amine-?(2)N,N']silver(I) (1/1).
| S-EPMC3344365 | biostudies-literature
Unknown Crystal structure of (pyridin-2-yl-methyl-idene)(tri-phenyl-meth-yl)amine.
| S-EPMC4257176 | biostudies-literature
Unknown Trichloridotris{N-[phen-yl(pyridin-2-yl)-methyl-idene]hydroxyl-amine-?N,N'}samarium(III).
| S-EPMC3297284 | biostudies-literature
Unknown Poly[bis-{μ-N'-[(pyridin-4-yl)methyl-idene]benzohydrazidato}copper(II)].
| S-EPMC3772419 | biostudies-literature
Unknown Trichloridotris{N-[phen-yl(pyridin-2-yl)methyl-idene]hydroxyl-amine-?(2)N,N'}neodymium(III).
| S-EPMC3344326 | biostudies-literature
Unknown catena-Poly[[silver(I)-?-N-[(pyridin-2-yl)meth-yl]pyridine-3-amine-?(2) N:N'] hexa-fluorido-phosphate].
| S-EPMC4051042 | biostudies-literature
Unknown Bis[(E)-N-(pyridin-3-yl-methyl-idene)hydroxyl-amine-?N(1)]silver(I) perchlorate.
| S-EPMC3379077 | biostudies-literature
Unknown Bis[?-(E)-N-(pyridin-3-yl-methyl-idene)hy-droxy-amine]-?(2) N (1):N (3);?(2) N (3):N (1)-bis-{[(E)-N-(pyridin-3-yl-methyl-idene-?N)hy-droxy-amine]-silver(I)} dinitrate.
| S-EPMC3588788 | biostudies-literature