Ontology highlight
ABSTRACT:
SUBMITTER: Mahmoudi A
PROVIDER: S-EPMC3470156 | biostudies-literature | 2012 Oct
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20120919 Pt 10
In the asymmetric unit of the title polymeric complex, {[CuI(C(11)H(9)N(3))]·0.5CH(3)CN}(n), there are two Cu(I) atoms, two N-[(pyridin-2-yl-κN)methyl-idene]pyridin-3-amine (PyPy) ligands and two I atoms. Both Cu(I) atoms have a distorted tetra-hedral geometry, each being coordinated by one I atom, two N atoms of one PyPy ligand and one N atom from an adjacent PyPy ligand. In the crystal, infinite helical chains of [Cu(2)(PyPy)(2)](n) are formed propagating along the b axis. These chains are lin ...[more]