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(1-{(E)-[Phen-yl(pyridin-2-yl-?N)methyl-idene]amino-?N}pyrrolidin-2-one-?O)bis-(thio-cyanato-?N)copper(II).


ABSTRACT: The Cu(II) atom in the title compound, [Cu(NCS)(2)(C(16)H(15)N(3)O)], is bonded to the N atoms of two thio-cyanate ions, and is N,N'-chelated by the Schiff base ligand. The four N atoms surround the metal atom to form a distorted square; the square environment is distorted towards a square pyramid by a long Cu?O inter-action. In the crystal, two C atoms of the pyrrolidin-2-one ring are disordered over two positions in a 1:1 ratio.

SUBMITTER: Kunnath RJ 

PROVIDER: S-EPMC3470172 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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(1-{(E)-[Phen-yl(pyridin-2-yl-κN)methyl-idene]amino-κN}pyrrolidin-2-one-κO)bis-(thio-cyanato-κN)copper(II).

Kunnath Roji J RJ   Prathapachandra Kurup M R MR   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20120926 Pt 10


The Cu(II) atom in the title compound, [Cu(NCS)(2)(C(16)H(15)N(3)O)], is bonded to the N atoms of two thio-cyanate ions, and is N,N'-chelated by the Schiff base ligand. The four N atoms surround the metal atom to form a distorted square; the square environment is distorted towards a square pyramid by a long Cu⋯O inter-action. In the crystal, two C atoms of the pyrrolidin-2-one ring are disordered over two positions in a 1:1 ratio. ...[more]

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