Unknown

Dataset Information

0

(2Z,2'Z)-Diethyl 3,3'-[butane-1,4-diylbis(aza-nedi-yl)]bis-(but-2-enoate).

ABSTRACT: The whole mol-ecule of the title ?-enamino-ester, C(16)H(28)N(2)O(4), is generated by a crystallographic inversion center, situated at the mid-point of the central C-C bond of the 1,4-diamino-butane segment. There are two intra-molecular N-H?O hydrogen bonds that generate S(6) ring motifs. This leads to the Z conformation about the C=C bonds [1.3756?(17)?Å]. The mol-ecule is S-shaped with the planar central 1,4-diamino-butane segment [maximum deviation for non H-atoms = 0.0058?(13)?Å] being inclined to the ethyl butyl-enonate fragment [C-C-O-C-C=C-C; maximum deviation = 0.0710?(12)?Å] by 15.56?(10)°. In the crystal, mol-ecules are linked via C-H?O inter-actions, leading to the formation of an undulating two-dimensional network lying parallel to the bc plane.

SUBMITTER: Harrad MA 

PROVIDER: S-EPMC3470214 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

(2Z,2'Z)-Diethyl 3,3'-[butane-1,4-diylbis(aza-nedi-yl)]bis-(but-2-enoate).

Harrad Mohamed Anouar MA   Boualy Brahim B   Ali Mustapha Ait MA   El Firdoussi Larbi L   Stoeckli-Evans Helen H  

Acta crystallographica. Section E, Structure reports online 20120905 Pt 10

The whole mol-ecule of the title β-enamino-ester, C(16)H(28)N(2)O(4), is generated by a crystallographic inversion center, situated at the mid-point of the central C-C bond of the 1,4-diamino-butane segment. There are two intra-molecular N-H⋯O hydrogen bonds that generate S(6) ring motifs. This leads to the Z conformation about the C=C bonds [1.3756 (17) Å]. The mol-ecule is S-shaped with the planar central 1,4-diamino-butane segment [maximum deviation for non H-atoms = 0.0058 (13) Å] being incl  ...[more]

Similar Datasets

Unknown [μ-Butane-1,4-diylbis(di-phenyl-phos-phane)-κ(2) P:P']bis-{[butane-1,4-diylbis(di-phenyl-phosphane)-κ(2) P,P']copper(I)} bis-(hexa-fluorido-phosphate) diethyl ether disolvate.
| S-EPMC4051095 | biostudies-literature
Unknown (E,E)-3,3'-Dimethyl-1,1'-diphenyl-4,4'-{[3-aza-pentane-1,5-diylbis(aza-nedi-yl)]bis-(phenyl-methyl-idyne)}di-1H-pyrazol-5(4H)-one.
| S-EPMC3011678 | biostudies-literature
Unknown 5,5'-Diphenyl-2,2'-[butane-1,4-diylbis(sulfanedi-yl)]bis-(1,3,4-oxadiazole).
| S-EPMC3009329 | biostudies-literature
Unknown 3,3'-(Butane-1,4-di-yl)diimidazole-1,1'-diium bis-(triiodide).
| S-EPMC2962153 | biostudies-literature
Unknown 5,5'-Bis(diethyl-amino)-2,2'-[butane-1,4-diyldioxy-bis(nitrilo-methyl-idyne)]-diphenol.
| S-EPMC2961048 | biostudies-literature
Unknown Dimethyl 3,3'-diphenyl-2,2'-[(S)-thio-phene-2,5-diylbis(carbonyl-aza-nedi-yl)]dipropano-ate tetra-hydro-furan monosolvate.
| S-EPMC2983431 | biostudies-literature
Unknown 3,3'-Dimethyl-1,1'-(butane-1,4-di-yl)diimidazolium bis-(tetra-fluoro-borate).
| S-EPMC2979393 | biostudies-literature
Unknown Dimethyl 3,3'-diphenyl-2,2'-[(S)-thio-phene-2,5-diylbis(carbonyl-aza-nedi-yl)]dipropano-ate.
| S-EPMC3007902 | biostudies-other
Unknown 3,3'-[(tert-Butoxy-carbon-yl)aza-nedi-yl]dipropanoic acid.
| S-EPMC2969698 | biostudies-literature
Unknown Dimethyl 2,2'-[butane-1,4-diylbis(sul-fanediyl)]dibenzoate.
| S-EPMC2971371 | biostudies-literature