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O,O'-Dimethyl (cyclo-hexyl-amido)-thio-phosphate.

ABSTRACT: The P atom in the title compound, C(8)H(18)NO(2)PS, is bonded in a distorted tetra-hedral PSO(2)N environment with bond angles in the range of 99.23?(5)-115.17?(4)°. The cyclo-hexane ring is disordered over two sets of sites with refined occupancies of 0.528?(5) and 0.472?(5). The ring in both disorder components adopts a chair conformation with the N-H group oriented equatorially. In the crystal, pairs of P=S?H-N hydrogen bonds form inversion dimers.

SUBMITTER: Sabbaghi F

PROVIDER: S-EPMC3470243 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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O,O'-Dimethyl (cyclo-hexyl-amido)-thio-phosphate.

Sabbaghi Fahimeh F Pourayoubi Mehrdad M Nečas Marek M

Acta crystallographica. Section E, Structure reports online 20120908 Pt 10

The P atom in the title compound, C(8)H(18)NO(2)PS, is bonded in a distorted tetra-hedral PSO(2)N environment with bond angles in the range of 99.23 (5)-115.17 (4)°. The cyclo-hexane ring is disordered over two sets of sites with refined occupancies of 0.528 (5) and 0.472 (5). The ring in both disorder components adopts a chair conformation with the N-H group oriented equatorially. In the crystal, pairs of P=S⋯H-N hydrogen bonds form inversion dimers. ...[more]

PMID: 23125687

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