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N-[(3RS,4RS)-1-Benzyl-4-methyl-piperidin-3-yl]-5-nitro-1-phenyl-sulfonyl-1H-pyrrolo-[2,3-b]pyridine-4-amine.

ABSTRACT: The pyrrolo-pyridine system in the title compound, C(27)H(29)N(5)O(4)S, is oriented at a dihedral angle of 71.20?(5)° towards the phenyl ring of the tosyl residue and at a dihedral angle of 45.43?(4)° towards the benzyl group. The structure shows an intra-molecular N-H?O and a weak intra-molecular N-H?N hydrogen bond. The piperidine ring adopts a chair conformation, with the cis substituents displaying a torsion angle of -54.59?(18)°.

SUBMITTER: Pfaffenrot E 

PROVIDER: S-EPMC3470400 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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N-[(3RS,4RS)-1-Benzyl-4-methyl-piperidin-3-yl]-5-nitro-1-phenyl-sulfonyl-1H-pyrrolo-[2,3-b]pyridine-4-amine.

Pfaffenrot Ellen E   Schollmeyer Dieter D   Laufer Stefan S  

Acta crystallographica. Section E, Structure reports online 20120929 Pt 10

The pyrrolo-pyridine system in the title compound, C(27)H(29)N(5)O(4)S, is oriented at a dihedral angle of 71.20 (5)° towards the phenyl ring of the tosyl residue and at a dihedral angle of 45.43 (4)° towards the benzyl group. The structure shows an intra-molecular N-H⋯O and a weak intra-molecular N-H⋯N hydrogen bond. The piperidine ring adopts a chair conformation, with the cis substituents displaying a torsion angle of -54.59 (18)°. ...[more]

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