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Highly sensitive NH3 detection based on organic field-effect transistors with tris(pentafluorophenyl)borane as receptor.

ABSTRACT: We have increased organic field-effect transistor (OFET) NH(3) response using tris(pentafluorophenyl)borane (TPFB) as a receptor. OFETs with this additive could detect concentrations of 450 ppb v/v, with a limit of detection of 350 ppb, the highest sensitivity reported to date for semiconductor films; in comparison, when triphenylmethane (TPM) or triphenylborane (TFB) was used as an additive, no obvious improvement in the sensitivity was observed. These OFETs also showed considerable selectivity with respect to common organic vapors and stability toward storage. Furthermore, excellent memory of exposure was achieved by keeping the exposed devices in a sealed container stored at -30 °C, the first such capability demonstrated with OFETs.

SUBMITTER: Huang W

PROVIDER: S-EPMC3476044 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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Highly sensitive NH3 detection based on organic field-effect transistors with tris(pentafluorophenyl)borane as receptor.

Huang Weiguo W Besar Kalpana K LeCover Rachel R Rule Ana María AM Breysse Patrick N PN Katz Howard E HE

Journal of the American Chemical Society 20120904 36

We have increased organic field-effect transistor (OFET) NH(3) response using tris(pentafluorophenyl)borane (TPFB) as a receptor. OFETs with this additive could detect concentrations of 450 ppb v/v, with a limit of detection of 350 ppb, the highest sensitivity reported to date for semiconductor films; in comparison, when triphenylmethane (TPM) or triphenylborane (TFB) was used as an additive, no obvious improvement in the sensitivity was observed. These OFETs also showed considerable selectivity ...[more]

PMID: 22934620

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