Ontology highlight
ABSTRACT:
SUBMITTER: Liu J
PROVIDER: S-EPMC3513965 | biostudies-literature | 2012
REPOSITORIES: biostudies-literature
Liu Jinxuan J Lukose Binit B Shekhah Osama O Arslan Hasan Kemal HK Weidler Peter P Gliemann Hartmut H Bräse Stefan S Grosjean Sylvain S Godt Adelheid A Feng Xinliang X Müllen Klaus K Magdau Ioan-Bogdan IB Heine Thomas T Wöll Christof C
Scientific reports 20121204
A novel class of metal organic frameworks (MOFs) has been synthesized from Cu-acetate and dicarboxylic acids using liquid phase epitaxy. The SURMOF-2 isoreticular series exhibits P4 symmetry, for the longest linker a channel-size of 3 × 3 nm(2) is obtained, one of the largest values reported for any MOF so far. High quality, ab-initio electronic structure calculations confirm the stability of a regular packing of (Cu(++))(2)- carboxylate paddle-wheel planes with P4 symmetry and reveal, that the ...[more]