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Poly[(?-1,3-thio-cyanato-?N,S)(iso-nicotin-ato-?N,O)(ethanol-?O)cadmium(II)].

ABSTRACT: In the crystal structure of the title compound, [Cd(NCS)(C(6)H(4)NO(2))(C(2)H(5)OH)](n), the Cd(2+) cation is coordinated by one N and two O atoms of two symmetry-related isonicotinate anions, one ethanol mol-ecule and two ?-1,3-bridging thio-cyanate anions in a distorted octa-hedral N(2)O(3)S geometry. The metal cations are ?-1,3-bridged via thio-cyanate anions into chains that are further connected into layers parallel to the ab plane by bridging isonicotinate anions. The layers are stacked along the c axis. The crystal structure is stabilized by O-H?O hydrogen bonds.

SUBMITTER: Neumann T

PROVIDER: S-EPMC3515102 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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Poly[(μ-1,3-thio-cyanato-κN,S)(iso-nicotin-ato-κN,O)(ethanol-κO)cadmium(II)].

Neumann Tristan T Werner Julia J Jess Inke I Näther Christian C

Acta crystallographica. Section E, Structure reports online 20121006 Pt 11

In the crystal structure of the title compound, [Cd(NCS)(C(6)H(4)NO(2))(C(2)H(5)OH)](n), the Cd(2+) cation is coordinated by one N and two O atoms of two symmetry-related isonicotinate anions, one ethanol mol-ecule and two μ-1,3-bridging thio-cyanate anions in a distorted octa-hedral N(2)O(3)S geometry. The metal cations are μ-1,3-bridged via thio-cyanate anions into chains that are further connected into layers parallel to the ab plane by bridging isonicotinate anions. The layers are stacked al ...[more]

PMID: 23284329

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