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Bis(diisopropyl-ammonium) hexa-chlorido-stannate(IV).

ABSTRACT: The title compound, (C(6)H(16)N)(2)[SnCl(6)], crystallizes with one diisopropyl-ammonium cation lying on a general position and the hexa-chloridostannate(IV) anion about a centre of inversion. The [SnCl(6)](2-) anion undergoes a slight distortion from octa-hedral symmetry as the result of the formation of four unforked charge-supported N-H?Cl hydrogen bonds. The hydrogen bonds between the cations and anions form layers perpendicular to [101]. These layers are built by 24-membered rings which can be classified with an R(8) (8)(24) graph-set descriptor. According to this hydrogen-bonding motif, the title compound is isostructural with (C(6)H(16)N)(2)[IrCl(6)].

SUBMITTER: Reiss GJ 

PROVIDER: S-EPMC3515144 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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Bis(diisopropyl-ammonium) hexa-chlorido-stannate(IV).

Reiss Guido J GJ   Helmbrecht Cora C  

Acta crystallographica. Section E, Structure reports online 20121024 Pt 11

The title compound, (C(6)H(16)N)(2)[SnCl(6)], crystallizes with one diisopropyl-ammonium cation lying on a general position and the hexa-chloridostannate(IV) anion about a centre of inversion. The [SnCl(6)](2-) anion undergoes a slight distortion from octa-hedral symmetry as the result of the formation of four unforked charge-supported N-H⋯Cl hydrogen bonds. The hydrogen bonds between the cations and anions form layers perpendicular to [101]. These layers are built by 24-membered rings which can  ...[more]

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