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Bis{2,4-dibromo-6-[(E)-(4-fluoro-benz-yl)imino-meth-yl]phenolato-?(2)N,O}zinc.

ABSTRACT: In the title Schiff base complex, [Zn(C(14)H(9)Br(2)FNO)(2)], the Zn(II) atom is located on a twofold rotation axis and is coordinated by two O and two N atoms from two symmetry-related bidentate Schiff base ligands in a compressed tetrahedral geometry. The bond lengths and bond angles are within normal ranges. The dihedral angle between the least-squares planes of the aromatic rings within each ligand is 82.76?(17)°.

SUBMITTER: Zhang D

PROVIDER: S-EPMC3515159 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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Bis{2,4-dibromo-6-[(E)-(4-fluoro-benz-yl)imino-meth-yl]phenolato-κ(2)N,O}zinc.

Zhang Dingjun D Yu Hong H Jin Yue-Bao YB Lei Ke-Wei KW

Acta crystallographica. Section E, Structure reports online 20121031 Pt 11

In the title Schiff base complex, [Zn(C(14)H(9)Br(2)FNO)(2)], the Zn(II) atom is located on a twofold rotation axis and is coordinated by two O and two N atoms from two symmetry-related bidentate Schiff base ligands in a compressed tetrahedral geometry. The bond lengths and bond angles are within normal ranges. The dihedral angle between the least-squares planes of the aromatic rings within each ligand is 82.76 (17)°. ...[more]

PMID: 23284386

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Bis{2,4-dibromo-6-[(E)-(4-fluoro-benz-yl)imino-meth-yl]phenolato-?(2)N,O}cobalt(II).

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