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1-Dodecyl-1H-benzo[d]imidazol-2(3H)-one.

ABSTRACT: In the title compound, C(19)H(30)N(2)O, the fused ring system is essentially planar, the maximum deviation from the mean plane being 0.013?(2)?Å for the N atom bearing the dodecyl chain. The 1-dodecyl group is almost perpendicular to the 1H-benzo[d]imidazol-2(3H)-one plane as indicated by the dihedral angle of 82.9?(2)°between planes through the fused ring system and the first three C atoms of the chain. The C-C-C-C torsion angles (about ±179°) of the dodecyl group indicate an anti-periplanar conformation. In the crystal, inversion dimers are formed by pairs of N-H?O hydrogen bonds.

SUBMITTER: Belaziz D

PROVIDER: S-EPMC3515176 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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1-Dodecyl-1H-benzo[d]imidazol-2(3H)-one.

Belaziz Dounia D Kandri Rodi Youssef Y Ouazzani Chahdi Fouad F Essassi El Mokhtar el M Saadi Mohamed M El Ammari Lahcen L

Acta crystallographica. Section E, Structure reports online 20121006 Pt 11

In the title compound, C(19)H(30)N(2)O, the fused ring system is essentially planar, the maximum deviation from the mean plane being 0.013 (2) Å for the N atom bearing the dodecyl chain. The 1-dodecyl group is almost perpendicular to the 1H-benzo[d]imidazol-2(3H)-one plane as indicated by the dihedral angle of 82.9 (2)°between planes through the fused ring system and the first three C atoms of the chain. The C-C-C-C torsion angles (about ±179°) of the dodecyl group indicate an anti-periplanar co ...[more]

PMID: 23284403

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