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Dibenzo[b,f][1,4]thia-zepin-11-yl-diethyl-amine.

ABSTRACT: In the title compound, C(17)H(18)N(2)S, the thia-zepine ring adopts a boat conformation and the dihedral angle between the benzene rings is 75.92?(5)°, resulting in a butterfly-like conformation. In the crystal, mol-ecules are connected via weak C(aromatic)-H?N contacts involving the imine N atom as acceptor and through a quite short C-H?? inter-action. The resulting mol-ecular chains propagate along the c-axis direction.

SUBMITTER: Altamura M

PROVIDER: S-EPMC3515236 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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Dibenzo[b,f][1,4]thia-zepin-11-yl-diethyl-amine.

Altamura Maria M Guidi Antonio A Jierry Loic L Paoli Paola P Rossi Patrizia P

Acta crystallographica. Section E, Structure reports online 20121013 Pt 11

In the title compound, C(17)H(18)N(2)S, the thia-zepine ring adopts a boat conformation and the dihedral angle between the benzene rings is 75.92 (5)°, resulting in a butterfly-like conformation. In the crystal, mol-ecules are connected via weak C(aromatic)-H⋯N contacts involving the imine N atom as acceptor and through a quite short C-H⋯π inter-action. The resulting mol-ecular chains propagate along the c-axis direction. ...[more]

PMID: 23284456

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