4-Bromo-2-[(E)-{[4-nitro-2-(trifluoro-meth-yl)phen-yl]imino}-meth-yl]phenol.

ABSTRACT: Except two F atoms of the -CF(3) group, the title compound, C(14)H(8)BrF(3)N(2)O(3), has an almost planar conformation, the dihedral angle between the aromatic rings being 3.60?(16)°. The mol-ecule adopts the enol-imine tautomeric form, with an intra-molecular O-H?N hydrogen bond, which generates an S(6) ring motif. In the crystal, face-to-face ?-? stacking [centroid-centroid distances = 3.669?(2) and 3.732?(2)?Å] between the aromatic rings of the mol-ecules, which lie in sheets parallel to (202), help to establish the packing.

SUBMITTER: Akkurt M 

PROVIDER: S-EPMC3515262 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature