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(E)-1-(4-Nitro-benzyl-idene)-2,2-diphenyl-hydrazine.

ABSTRACT: The asymmetric unit of the title compound, C(19)H(15)N(3)O(2), contains two mol-ecules, both of which show an E conformation of the imine bond. The dihedral angles between the phenyl rings in the phenyl-hydrazine groups are 86.09?(6) and 83.41?(5)° in the two mol-ecules. The 4-nitrobenzene rings show torsion angles of 4.4?(2) and 10.9?(2)° from the two C=N-N planes. In the crystal, C-H?? inter-actions and C-H?O hydrogen bonds are observed growing along the a, b and c axes, resulting in a complex supramolecular array.

SUBMITTER: Mendoza A

PROVIDER: S-EPMC3515317 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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(E)-1-(4-Nitro-benzyl-idene)-2,2-diphenyl-hydrazine.

Mendoza Angel A Meléndrez-Luevano Ruth R Cabrera-Vivas Blanca M BM Acoltzi-X Claudia C Flores-Alamo Marcos M

Acta crystallographica. Section E, Structure reports online 20121031 Pt 11

The asymmetric unit of the title compound, C(19)H(15)N(3)O(2), contains two mol-ecules, both of which show an E conformation of the imine bond. The dihedral angles between the phenyl rings in the phenyl-hydrazine groups are 86.09 (6) and 83.41 (5)° in the two mol-ecules. The 4-nitrobenzene rings show torsion angles of 4.4 (2) and 10.9 (2)° from the two C=N-N planes. In the crystal, C-H⋯π inter-actions and C-H⋯O hydrogen bonds are observed growing along the a, b and c axes, resulting in a complex ...[more]

PMID: 23284537

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