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Bis[?-4-(4-carb-oxy-phen-oxy)phthalato]bis-[triaqua-cobalt(II)].

ABSTRACT: The dinuclear title complex, [Co(2)(C(15)H(8)O(7))(2)(H(2)O)(6)], lies across an inversion center. The unique Co(II) ion is coordinated in a slightly distorted octa-hedral coordination geometry by two O atoms from a chelating 4-(carb-oxy-phen-oxy)phthalate ligand, three water O atoms and a further O atom from a bridging carboxyl-ate group of a symmetry-related 4-(carb-oxy-phen-oxy)phthalate ligand. In the crystal, O-H?O hydrogen bonds link the mol-ecules into a three-dimensional network.

SUBMITTER: Wang L 

PROVIDER: S-EPMC3569198 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

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Bis[μ-4-(4-carb-oxy-phen-oxy)phthalato]bis-[triaqua-cobalt(II)].

Wang Liang L  

Acta crystallographica. Section E, Structure reports online 20130112 Pt 2

The dinuclear title complex, [Co(2)(C(15)H(8)O(7))(2)(H(2)O)(6)], lies across an inversion center. The unique Co(II) ion is coordinated in a slightly distorted octa-hedral coordination geometry by two O atoms from a chelating 4-(carb-oxy-phen-oxy)phthalate ligand, three water O atoms and a further O atom from a bridging carboxyl-ate group of a symmetry-related 4-(carb-oxy-phen-oxy)phthalate ligand. In the crystal, O-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network. ...[more]

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