Unknown

Dataset Information

0

Catena-Poly[[[triaqua-[3-(4-carb-oxy-phen-oxy)phthalato-?O(2)]manganese(II)]-?-4,4'-bipyridine-?(2)N:N'] 4,4'-bipyridine monosolvate dihydrate].


ABSTRACT: In the title compound, {[Mn(C(15)H(8)O(7))(C(10)H(8)N(2))(H(2)O)(3)]·C(10)H(8)N(2)·2H(2)O}(n), the bridging mode of the coordinating 4,4'-bipyridine ligands leads to the formation of polymeric zigzag chains parallel to [0-11]. The chains are separated by 4,4'-bipyridine and water solvent mol-ecules. Within a chain, the Mn(II) atom is six-coordinated by two N atoms of the bridging 4,4'-bipyridine ligands, three water O atoms and one carboxyl-ate O atom of a single deprotonated 3-(4-carb-oxy-phen-oxy)phthalic acid ligand. Both coordinating and solvent 4,4'-bipyridine mol-ecules are situated on centres of inversion. An intricate network of O-H?O and O-H?N hydrogen bonds involving the carb-oxy group, the coordinating water mol-ecules and the two types of solvent mol-ecules leads to the formation of a three-dimensional network.

SUBMITTER: Sun W 

PROVIDER: S-EPMC3569212 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

altmetric image

Publications

catena-Poly[[[triaqua-[3-(4-carb-oxy-phen-oxy)phthalato-κO(2)]manganese(II)]-μ-4,4'-bipyridine-κ(2)N:N'] 4,4'-bipyridine monosolvate dihydrate].

Sun Wei W  

Acta crystallographica. Section E, Structure reports online 20130123 Pt 2


In the title compound, {[Mn(C(15)H(8)O(7))(C(10)H(8)N(2))(H(2)O)(3)]·C(10)H(8)N(2)·2H(2)O}(n), the bridging mode of the coordinating 4,4'-bipyridine ligands leads to the formation of polymeric zigzag chains parallel to [0-11]. The chains are separated by 4,4'-bipyridine and water solvent mol-ecules. Within a chain, the Mn(II) atom is six-coordinated by two N atoms of the bridging 4,4'-bipyridine ligands, three water O atoms and one carboxyl-ate O atom of a single deprotonated 3-(4-carb-oxy-phen-  ...[more]

Similar Datasets

| S-EPMC2977433 | biostudies-literature
| S-EPMC3569198 | biostudies-literature
| S-EPMC3050356 | biostudies-literature
| S-EPMC2977154 | biostudies-literature
| S-EPMC2980029 | biostudies-literature
| S-EPMC2980147 | biostudies-literature
| S-EPMC2959782 | biostudies-literature
| S-EPMC3120441 | biostudies-literature
| S-EPMC3011421 | biostudies-literature
| S-EPMC2970467 | biostudies-literature