Unknown

Dataset Information

0

(2,3-Difluoro-phen-yl)(4-tosyl-piperazin-1-yl)methanone.

ABSTRACT: In the title compound, C(18)H(18)F(2)N(2)O(3)S, the piperazine ring adopts a chair conformation. The dihedral angle between the sulfonyl-bound benzene ring and the best fit plane throught the six non-H atoms of the piperazine ring is 69.4?(2)°, while those between the fluoro-benzene and sulfonyl rings and the fluoro-benzene and piperazine rings are 30.97?(2) and 75.98?(2)°, respectively. In the crystal, mol-ecules are connected to form a tetra-meric unit through C-H?O hydrogen bonds. The structure is further stabilized by weak inter-molecular C-H?F inter-actions, generating C(8) and C(7) chains running along [100].

SUBMITTER: Sreenivasa S 

PROVIDER: S-EPMC3569247 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

(2,3-Difluoro-phen-yl)(4-tosyl-piperazin-1-yl)methanone.

Sreenivasa S S   Manojkumar K E KE   Suchetan P A PA   Tonannavar J J   Chavan Yashshwita Y   Palakshamurthy B S BS  

Acta crystallographica. Section E, Structure reports online 20130104 Pt 2

In the title compound, C(18)H(18)F(2)N(2)O(3)S, the piperazine ring adopts a chair conformation. The dihedral angle between the sulfonyl-bound benzene ring and the best fit plane throught the six non-H atoms of the piperazine ring is 69.4 (2)°, while those between the fluoro-benzene and sulfonyl rings and the fluoro-benzene and piperazine rings are 30.97 (2) and 75.98 (2)°, respectively. In the crystal, mol-ecules are connected to form a tetra-meric unit through C-H⋯O hydrogen bonds. The structu  ...[more]

Similar Datasets

Unknown (2,4-Difluoro-phen-yl)[1-(1H-1,2,4-triazol-1-yl)cyclo-prop-yl]methanone.
| S-EPMC3247327 | biostudies-literature
Unknown (2,6-Difluoro-phen-yl)(4-methyl-piperidin-1-yl)methanone.
| S-EPMC3200831 | biostudies-other
Unknown 4-(2,3-Di-chloro-phen-yl)piperazin-1-ium picrate.
| S-EPMC9462331 | biostudies-literature
Unknown 4-(2,3-Dimethyl-phen-yl)piperazin-1-ium chloride monohydrate.
| S-EPMC2961679 | biostudies-literature
Unknown (11-Methyl-pyrido[2,3-b][1,4]benzo-diazepin-6-yl)(phen-yl)methanone.
| S-EPMC3008030 | biostudies-literature
Unknown (3-Benzoyl-phen-yl)(phen-yl)methanone.
| S-EPMC3200948 | biostudies-literature
Unknown [4-(All-yloxy)phen-yl](phen-yl)methanone.
| S-EPMC4120571 | biostudies-literature
Unknown 2-(2,3-Difluoro-phen-yl)ethyl toluene-4-sulfonate.
| S-EPMC2979761 | biostudies-other
Unknown (4-Bromo-3,5-dimethyl-1H-pyrazol-1-yl)(2,6-difluoro-phen-yl)methanone.
| S-EPMC2980109 | biostudies-other
Unknown (5-Bromo-2-hydroxy-phen-yl)(phen-yl)methanone.
| S-EPMC2959262 | biostudies-literature