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2-Chloro-N-methyl-N-[2-(methyl-amino)-phen-yl]acetamide.

ABSTRACT: The title compound, C(10)H(13)ClN(2)O, was obtained as a by-product in the reaction of 2-chloro-methyl-1H-benzimidazole, dimethyl sulfate and toluene to synthesise 2-chloro-methyl-1-methyl-benzimidazole. The dihedral angle between the benzene ring and the acetamide group is 89.72 ?(6)° while that between the aromatic ring and the chloracetyl group is 84.40?(4)°. In the crystal, adjacent mol-ecules are linked by pairs of N-H?O hydrogen bonds into inversion dimers.

SUBMITTER: Bai YB 

PROVIDER: S-EPMC3569763 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

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2-Chloro-N-methyl-N-[2-(methyl-amino)-phen-yl]acetamide.

Bai Yu-Bin YB   Chen Xia-Hui XH   Ma Ya-Tuan YT   Zhang An-Ling AL   Gao Jin-Ming JM  

Acta crystallographica. Section E, Structure reports online 20130112 Pt 2

The title compound, C(10)H(13)ClN(2)O, was obtained as a by-product in the reaction of 2-chloro-methyl-1H-benzimidazole, dimethyl sulfate and toluene to synthesise 2-chloro-methyl-1-methyl-benzimidazole. The dihedral angle between the benzene ring and the acetamide group is 89.72  (6)° while that between the aromatic ring and the chloracetyl group is 84.40 (4)°. In the crystal, adjacent mol-ecules are linked by pairs of N-H⋯O hydrogen bonds into inversion dimers. ...[more]

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