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3-Chloro-4-fluoro-anilinium picrate.


ABSTRACT: In the title picrate salt of a dihalogenated aniline derivative, C(6)H(6)ClF(+)·C(6)H(2)N(3)O(7) (-), the intra-cyclic C-C-C angles in the picrate anion cover a broad range [111.95?(12)-125.38?(13)°], while those in the aromatic cation span a much narrower range [118.25?(14)-122.33?(13)°]. In the crystal, classical N-H?O hydrogen bonds, as well as C-H?O contacts, connect the ions into layers parallel to (001).

SUBMITTER: Sarojini BK 

PROVIDER: S-EPMC3569773 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

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3-Chloro-4-fluoro-anilinium picrate.

Sarojini Balladka K BK   Narayana Badiadka B   Yathirajan Hemmige S HS   Gerber Thomas T   van Brecht Benjamin B   Betz Richard R  

Acta crystallographica. Section E, Structure reports online 20130116 Pt 2


In the title picrate salt of a dihalogenated aniline derivative, C(6)H(6)ClF(+)·C(6)H(2)N(3)O(7) (-), the intra-cyclic C-C-C angles in the picrate anion cover a broad range [111.95 (12)-125.38 (13)°], while those in the aromatic cation span a much narrower range [118.25 (14)-122.33 (13)°]. In the crystal, classical N-H⋯O hydrogen bonds, as well as C-H⋯O contacts, connect the ions into layers parallel to (001). ...[more]

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