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5,11-Dimethyl-6,12-dimeth-oxy-indolo[3,2-b]carbazole.

ABSTRACT: The title compound, C(22)H(20)N(2)O(2), was prepared in a twofold Cadogan cyclization followed by double N-methyl-ation. The crystal structure is characterized by a zigzag arrangement of centrosymmetric mol-ecules. The indolocarbazole framework is essentially planar [maximum deviation = 0.028?(2)?Å] and the meth-oxy groups are orthogonal to this plane [C-C-O-C torsion angle = -88.2?(2)°]. The lengths of the C-N bonds are nearly identical and all C-C bonds of the pyrrole subunit are significantly longer than the C-C bonds in the benzene rings.

SUBMITTER: Wrobel N

PROVIDER: S-EPMC3569787 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

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5,11-Dimethyl-6,12-dimeth-oxy-indolo[3,2-b]carbazole.

Wrobel Norma N Witulski Bernhard B Schollmeyer Dieter D Detert Heiner H

Acta crystallographica. Section E, Structure reports online 20130119 Pt 2

The title compound, C(22)H(20)N(2)O(2), was prepared in a twofold Cadogan cyclization followed by double N-methyl-ation. The crystal structure is characterized by a zigzag arrangement of centrosymmetric mol-ecules. The indolocarbazole framework is essentially planar [maximum deviation = 0.028 (2) Å] and the meth-oxy groups are orthogonal to this plane [C-C-O-C torsion angle = -88.2 (2)°]. The lengths of the C-N bonds are nearly identical and all C-C bonds of the pyrrole subunit are significantly ...[more]

PMID: 23424533

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