Unknown

Dataset Information

0

5,11-Dimethyl-6,12-dimeth-oxy-indolo[3,2-b]carbazole.


ABSTRACT: The title compound, C(22)H(20)N(2)O(2), was prepared in a twofold Cadogan cyclization followed by double N-methyl-ation. The crystal structure is characterized by a zigzag arrangement of centrosymmetric mol-ecules. The indolocarbazole framework is essentially planar [maximum deviation = 0.028?(2)?Å] and the meth-oxy groups are orthogonal to this plane [C-C-O-C torsion angle = -88.2?(2)°]. The lengths of the C-N bonds are nearly identical and all C-C bonds of the pyrrole subunit are significantly longer than the C-C bonds in the benzene rings.

SUBMITTER: Wrobel N 

PROVIDER: S-EPMC3569787 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

altmetric image

Publications

5,11-Dimethyl-6,12-dimeth-oxy-indolo[3,2-b]carbazole.

Wrobel Norma N   Witulski Bernhard B   Schollmeyer Dieter D   Detert Heiner H  

Acta crystallographica. Section E, Structure reports online 20130119 Pt 2


The title compound, C(22)H(20)N(2)O(2), was prepared in a twofold Cadogan cyclization followed by double N-methyl-ation. The crystal structure is characterized by a zigzag arrangement of centrosymmetric mol-ecules. The indolocarbazole framework is essentially planar [maximum deviation = 0.028 (2) Å] and the meth-oxy groups are orthogonal to this plane [C-C-O-C torsion angle = -88.2 (2)°]. The lengths of the C-N bonds are nearly identical and all C-C bonds of the pyrrole subunit are significantly  ...[more]

Similar Datasets

| S-EPMC3588340 | biostudies-literature
| S-EPMC2960302 | biostudies-literature
| S-EPMC2979030 | biostudies-literature
| S-EPMC3254282 | biostudies-literature
| S-EPMC3006796 | biostudies-literature
| S-EPMC3629629 | biostudies-literature
| S-EPMC3201239 | biostudies-literature
| S-EPMC2979507 | biostudies-other