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2-[4-(Trifluoro-meth-oxy)phen-yl]-1H-benzimidazole.

ABSTRACT: In the title compound, C(14)H(9)F(3)N(2)O, the best planes of the benzimidazole group and benzene ring form a dihedral angle of 26.68?(3)°. In the crystal, N-H?N hydrogen bonds link the mol-ecules into infinite chains parallel to the c axis. Stacking inter-actions between the benzimidazole groups [centroid-centroid distance = 3.594?(5)?Å] assemble the mol-ecules into layers parallel to (100). The trifluoro-methyl group is disordered over three sets of sites with site-occupancy factors of 0.787?(4), 0.107?(7) and 0.106?(7).

SUBMITTER: Fathima N

PROVIDER: S-EPMC3569794 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

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2-[4-(Trifluoro-meth-oxy)phen-yl]-1H-benzimidazole.

Fathima Nikhath N Krishnamurthy M S MS Begum Noor Shahina NS

Acta crystallographica. Section E, Structure reports online 20130119 Pt 2

In the title compound, C(14)H(9)F(3)N(2)O, the best planes of the benzimidazole group and benzene ring form a dihedral angle of 26.68 (3)°. In the crystal, N-H⋯N hydrogen bonds link the mol-ecules into infinite chains parallel to the c axis. Stacking inter-actions between the benzimidazole groups [centroid-centroid distance = 3.594 (5) Å] assemble the mol-ecules into layers parallel to (100). The trifluoro-methyl group is disordered over three sets of sites with site-occupancy factors of 0.787 ( ...[more]

PMID: 23424540

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