Ontology highlight
ABSTRACT:
SUBMITTER: Ren H
PROVIDER: S-EPMC3582941 | biostudies-literature | 2013 Jan
REPOSITORIES: biostudies-literature
Organic letters 20121224 2
The catalytic asymmetric aminoallylation of chiral aldehydes is developed as a new method for the catalyst controlled synthesis of syn- and anti-1,3-aminoalcohols. This methodology is highlighted in the synthesis of the sedum alkaloids (+)-sedridine and (+)-allosedridine both of which have their final carbon incorporated during closure of the piperidine ring via a hydroformylation with formaldehyde. ...[more]