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6-Phenyl-benzo[d]naphtho-[2,3-b]thio-phene.

ABSTRACT: In the title compound, C22H14S, the r.m.s. deviation from the mean plane of the four-fused-ring naphtho-thio-phene unit is 0.056?Å. The dihedral angle between the naphtho-thio-phene plane and the pendant phenyl ring is 67.24?(6)°. In the crystal, weak C-H?? and ?-? stacking [minimum centroid-centroid separation = 3.7466?(10)?Å] inter-actions are observed, which together lead to (010) sheets.

SUBMITTER: Silambarasan V

PROVIDER: S-EPMC3588245 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

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6-Phenyl-benzo[d]naphtho-[2,3-b]thio-phene.

Silambarasan V V Srinivasan T T Sivasakthikumaran R R Mohanakrishnan A K AK Velmurugan D D

Acta crystallographica. Section E, Structure reports online 20121208 Pt 1

In the title compound, C22H14S, the r.m.s. deviation from the mean plane of the four-fused-ring naphtho-thio-phene unit is 0.056 Å. The dihedral angle between the naphtho-thio-phene plane and the pendant phenyl ring is 67.24 (6)°. In the crystal, weak C-H⋯π and π-π stacking [minimum centroid-centroid separation = 3.7466 (10) Å] inter-actions are observed, which together lead to (010) sheets. ...[more]

PMID: 23476423

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Crystal structure of 6-(p-tol-yl)benzo[b]naphtho[2,3-d]thio-phene and of an ortho-rhom-bic polymorph of 7-phenyl-anthra[2,3-b]benzo[d]thio-phene.

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