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2-(4-Meth-oxy-phen-yl)-1-pentyl-4,5-di-phenyl-1H-imidazole.

ABSTRACT: The title compound, C27H28N2O, is a lophine (2,4,5-triphenyl-1H-imidazole) derivative with an n-pentyl chain on the amine N atom and a 4-meth-oxy substituent on the benzene ring. The two phenyl and meth-oxy-benzene rings are inclined to the imidazole ring at angles of 25.32?(7), 76.79?(5) and 35.42?(7)°, respectively, while the meth-oxy substituent lies close to the plane of its benzene ring, with a maximum deviation of 0.126?(3)?Å for the meth-oxy C atom. In the crystal, inversion dimers linked by pairs of C-H?O hydrogen bonds generate R2(2)(22) loops. These dimers are stacked along the a-axis direction.

SUBMITTER: Simpson J 

PROVIDER: S-EPMC3588259 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

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2-(4-Meth-oxy-phen-yl)-1-pentyl-4,5-di-phenyl-1H-imidazole.

Simpson Jim J   Mohamed Shaaban K SK   Marzouk Adel A AA   Talybov Avtandil H AH   Abdelhamid Antar A AA  

Acta crystallographica. Section E, Structure reports online 20121205 Pt 1

The title compound, C27H28N2O, is a lophine (2,4,5-triphenyl-1H-imidazole) derivative with an n-pentyl chain on the amine N atom and a 4-meth-oxy substituent on the benzene ring. The two phenyl and meth-oxy-benzene rings are inclined to the imidazole ring at angles of 25.32 (7), 76.79 (5) and 35.42 (7)°, respectively, while the meth-oxy substituent lies close to the plane of its benzene ring, with a maximum deviation of 0.126 (3) Å for the meth-oxy C atom. In the crystal, inversion dimers linked  ...[more]

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