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4-Meth-oxy-benzamidinium bromide.

ABSTRACT: The title salt, C8H11N2O(+)·Br(-), was synthesized by the reaction between 4-meth-oxy-benzamidine (4-amidino-anisole) and hydro-bromic acid. In the cation, the amidinium group has two similar C-N bonds [1.304?(2) and 1.316?(2)?Å], and its plane forms a dihedral angle of 31.08?(5)° with the benzene ring. The ions are associated in the crystal into a three-dimension hydrogen-bonded supra-molecular network featuring N-H(+)?Br(-) inter-actions.

SUBMITTER: Irrera S

PROVIDER: S-EPMC3588269 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

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4-Meth-oxy-benzamidinium bromide.

Irrera Simona S Portalone Gustavo G

Acta crystallographica. Section E, Structure reports online 20121208 Pt 1

The title salt, C8H11N2O(+)·Br(-), was synthesized by the reaction between 4-meth-oxy-benzamidine (4-amidino-anisole) and hydro-bromic acid. In the cation, the amidinium group has two similar C-N bonds [1.304 (2) and 1.316 (2) Å], and its plane forms a dihedral angle of 31.08 (5)° with the benzene ring. The ions are associated in the crystal into a three-dimension hydrogen-bonded supra-molecular network featuring N-H(+)⋯Br(-) inter-actions. ...[more]

PMID: 23476438

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