Ontology highlight
ABSTRACT:
SUBMITTER: Apostolidis C
PROVIDER: S-EPMC3588273 | biostudies-literature | 2013 Jan
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20121208 Pt 1
In the colourless title compound, [Pr(CF3O3S)3(CH3CN)3] n , the three trifluoro-methane-sulfonate anions form three bridges via O:O'-coordination between two Pr(III) atoms. The structure contains [Pr(NCMe)3-μ2(OTf)3-Pr(NCMe)3-μ2(OTf)3] n (NCMe is acetonitrile; OTf is trifluoromethanesulfonate) chains parallel to the a axis. The Pr(III) atom is nine-coordinate in a distorted tricapped trigonal-prismatic environment. ...[more]