Unknown

Dataset Information

0

1-(4-Nitro-phen-yl)-1H-imidazol-3-ium chloride.

ABSTRACT: In the title salt, C9H8N3O2(+)·Cl(-), the least-squares planes of the imidazolium and benzene rings are almost coplanar, making a dihedral angle of 4.59?(1)°. In the crystal, the chloride anion links the organic mol-ecules through N-H?Cl hydrogen bonds, forming chains that run diagonally across the bc face, which compliment strong C-H?O hydrogen bonds between neighbouring mol-ecules. These chains are connected to adjacent chains through two weak C-H?Cl inter-actions, resulting in hydrogen-bonded sheets extending along the b and c axes. The absolute structure of the title compound was determined using a Flack x parameter of 0.00?(6) and a Hooft y parameter of 0.03?(2).

SUBMITTER: Ibrahim H 

PROVIDER: S-EPMC3588291 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

1-(4-Nitro-phen-yl)-1H-imidazol-3-ium chloride.

Ibrahim Halliru H   Bala Muhammad D MD  

Acta crystallographica. Section E, Structure reports online 20121219 Pt 1

In the title salt, C9H8N3O2(+)·Cl(-), the least-squares planes of the imidazolium and benzene rings are almost coplanar, making a dihedral angle of 4.59 (1)°. In the crystal, the chloride anion links the organic mol-ecules through N-H⋯Cl hydrogen bonds, forming chains that run diagonally across the bc face, which compliment strong C-H⋯O hydrogen bonds between neighbouring mol-ecules. These chains are connected to adjacent chains through two weak C-H⋯Cl inter-actions, resulting in hydrogen-bonded  ...[more]

Similar Datasets

Unknown 2-(3-Nitro-phen-yl)-4,5-diphenyl-1H-imidazol-3-ium chloride.
| S-EPMC2959275 | biostudies-literature
Unknown 2-(4-Nitro-phen-yl)-4,5-diphenyl-1H-imidazol-3-ium chloride.
| S-EPMC2969499 | biostudies-literature
Unknown 1-(4-Carb-oxy-phen-yl)-1H-imidazol-3-ium chloride dihydrate.
| S-EPMC3051584 | biostudies-literature
Unknown 1,3-Bis(2,6-diisopropyl-phen-yl)-1H-imidazol-3-ium chloride dichloro-methane disolvate.
| S-EPMC3379413 | biostudies-literature
Unknown 2-(3-Nitro-phen-yl)-4,5-diphenyl-1H-imidazol-3-ium nitrate.
| S-EPMC2969496 | biostudies-other
Unknown 2-[4-(4,5-Dihydro-1H-imidazol-2-yl)phen-yl]-4,5-dihydro-1H-imidazol-3-ium 4-amino-benzoate.
| S-EPMC3050166 | biostudies-literature
Unknown 1,3-Bis(2-anilino-2-oxoeth-yl)-1H-imidazol-3-ium chloride.
| S-EPMC3394023 | biostudies-literature
Unknown 1,3-Bis(2,6-diisopropyl-phen-yl)-4,5-dihydro-1H-imidazol-3-ium triiodide.
| S-EPMC3011707 | biostudies-literature
Unknown 1,3-Bis(2-anilino-2-oxoeth-yl)-1H-imidazol-3-ium chloride acetonitrile monosolvate.
| S-EPMC3239007 | biostudies-literature
Unknown 1,3-Bis(2,6-diisopropyl-phen-yl)-1H-imidazol-3-ium bromide dichloro-methane disolvate.
| S-EPMC3379414 | biostudies-literature