Unknown

Dataset Information

0

2-(Adamantan-1-yl)-1,3-bis-(4-methyl-phen-yl)propan-2-ol.

ABSTRACT: The conformation of the title compound, C27H34O, is stabilized by a weak intra-molecular C-H?? inter-action. The dihedral angle between the benzene rings is 54.79?(4)°. The adamantane cage consists of three fused cyclo-hexane rings in classical chair conformations, with C-C-C angles in the range 107.75?(10)-111.35?(9)°. Although the mol-ecule contains a hy-droxy group as a conceivable hydrogen-bond donor, this group is sterically hindered by bulky substituents and no hydrogen bonds are observed in the crystal structure.

SUBMITTER: Babjakova E 

PROVIDER: S-EPMC3588353 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

2-(Adamantan-1-yl)-1,3-bis-(4-methyl-phen-yl)propan-2-ol.

Babjaková Eva E   Bartoš Peter P   Vícha Robert R  

Acta crystallographica. Section E, Structure reports online 20121219 Pt 1

The conformation of the title compound, C27H34O, is stabilized by a weak intra-molecular C-H⋯π inter-action. The dihedral angle between the benzene rings is 54.79 (4)°. The adamantane cage consists of three fused cyclo-hexane rings in classical chair conformations, with C-C-C angles in the range 107.75 (10)-111.35 (9)°. Although the mol-ecule contains a hy-droxy group as a conceivable hydrogen-bond donor, this group is sterically hindered by bulky substituents and no hydrogen bonds are observed  ...[more]

Similar Datasets

Unknown 1,3-Bis(2-nitro-phen-oxy)propan-2-ol.
| S-EPMC3051473 | biostudies-literature
Unknown 1,3-Bis{[(4-methyl-phen-yl)sulfon-yl]-oxy}propan-2-yl 4-methyl-benzene-sulfonate.
| S-EPMC3297952 | biostudies-literature
Unknown 2-(5-Bromo-2-methyl-phen-yl)propan-2-ol.
| S-EPMC3009192 | biostudies-literature
Unknown 2-(4-Methyl-phen-yl)-1-(phenyl-sulfon-yl)propan-2-ol.
| S-EPMC3247583 | biostudies-literature
Unknown 1-Methyl-amino-3-(2,4,6-trimethyl-phen-yl)propan-2-ol.
| S-EPMC3099974 | biostudies-literature
Unknown (S)-2-(1-Methyl-indolin-2-yl)-1,3-diphenyl-propan-2-ol.
| S-EPMC3120338 | biostudies-literature
Unknown 2,3-Dibromo-1,3-bis-(4-chloro-phen-yl)propan-1-one.
| S-EPMC3011542 | biostudies-literature
Unknown 2,3-Dibromo-1,3-bis-(4-fluoro-phen-yl)propan-1-one.
| S-EPMC3007578 | biostudies-literature
Unknown 2-[2,6-Bis(propan-2-yl)phen-yl]-1,3-di-cyclo-hexyl-guanidine.
| S-EPMC4120537 | biostudies-literature
Unknown 2-(2-Benzyl-phen-yl)propan-2-ol.
| S-EPMC3238955 | biostudies-literature