The Mg member of the isotypic series MTe6O13.
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ABSTRACT:
SUBMITTER: Shirkhanlou M
PROVIDER: S-EPMC3588438 | biostudies-literature | 2013 Mar
REPOSITORIES: biostudies-literature
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The Mg member of the isotypic series MTe6O13.
Shirkhanlou Mahdi M Weil Matthias M
Acta crystallographica. Section E, Structure reports online 20130213 Pt 3
MgTe6O13, magnesium hexa-tellurate(IV), is isotypic with the structures of divalent first-row transition metal analogues MTe6O13 (M = Mn, Fe, Co, Ni and Zn). The asymmetric unit contains one Mg, two Te and five O atoms of which the Mg and one O atom lie on a threefold rotation axis. The structure is made up from slightly distorted [MgO6] octa-hedra (isolated from each other), distorted [TeO4] bis-phenoids and [TeO4 + 1] tetra-gonal pyramids sharing corners and edges. This arrangement leads to th ...[more]
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