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2-[3-Meth-oxy-5-(pyrimidin-2-yl)phen-yl]pyrimidine.

ABSTRACT: The title compound, C15H12N4O, was synthesized by a standard Suzuki cross-coupling reaction. The terminal pyrim-idine rings are rotated at dihedral angles of 12.06?(4) and -13.13?(4)° with respect to the central benzene ring. In the crystal, the mol-ecules are connected by two kinds of C-H?N hydrogen bonds, forming zigzag chains along the c axis. Weak ?-? inter-actions between the benzene and one of the pyrimidine rings are also found and stack the mol-ecules along the b axis [centroid-centroid distance = 4.112?(3)?Å].

SUBMITTER: Hu J

PROVIDER: S-EPMC3588471 | biostudies-literature | 2013 Mar

REPOSITORIES: biostudies-literature

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2-[3-Meth-oxy-5-(pyrimidin-2-yl)phen-yl]pyrimidine.

Hu Jiena J Wu Yang Y Zhang Dengqing D Li Xianying X Jin Wusong W

Acta crystallographica. Section E, Structure reports online 20130202 Pt 3

The title compound, C15H12N4O, was synthesized by a standard Suzuki cross-coupling reaction. The terminal pyrim-idine rings are rotated at dihedral angles of 12.06 (4) and -13.13 (4)° with respect to the central benzene ring. In the crystal, the mol-ecules are connected by two kinds of C-H⋯N hydrogen bonds, forming zigzag chains along the c axis. Weak π-π inter-actions between the benzene and one of the pyrimidine rings are also found and stack the mol-ecules along the b axis [centroid-centroid ...[more]

PMID: 23476528

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