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Methyl 11-hy-droxy-9-[1-(4-meth-oxy-phen-yl)-4-oxo-3-phenyl-azetidin-2-yl]-18-oxo-10-oxa-2-aza-penta-cyclo-[9.7.0.0(1,8).0(2,6).0(12,17)]octa-deca-12(17),13,15-triene-8-carboxyl-ate.


ABSTRACT: In the title compound, C34H32N2O7, the furan ring adopts a twist conformation and both the pyrrolidine rings adopt envelope conformations with O and C as flap atoms. The ?-lactam ring makes a dihedral angles of 80.20?(10)° with the furan ring, of 75.55?(10)° with the pyrrolidine ring, of 12.26?(10)° with the meth-oxy-phenyl ring and of 73.77?(13)° with the phenyl ring. The O atom attached to the ?-lactam ring deviates by 0.0385?(13)?Å from the ring plane. The mol-ecular conformation is stabilized by intra-molecular O-H?N and C-H?O hydrogen bonds. The packing of the crystal is stabilized by inter-molecular C-H?O hydrogen bonds, which form a chain running along the b axis.

SUBMITTER: Suhitha S 

PROVIDER: S-EPMC3588541 | biostudies-literature | 2013 Mar

REPOSITORIES: biostudies-literature

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Methyl 11-hy-droxy-9-[1-(4-meth-oxy-phen-yl)-4-oxo-3-phenyl-azetidin-2-yl]-18-oxo-10-oxa-2-aza-penta-cyclo-[9.7.0.0(1,8).0(2,6).0(12,17)]octa-deca-12(17),13,15-triene-8-carboxyl-ate.

Suhitha Sivasubramanian S   Srinivasan Thothadri T   Rajesh Raju R   Raghunathan Raghavachary R   Velmurugan Devadasan D  

Acta crystallographica. Section E, Structure reports online 20130223 Pt 3


In the title compound, C34H32N2O7, the furan ring adopts a twist conformation and both the pyrrolidine rings adopt envelope conformations with O and C as flap atoms. The β-lactam ring makes a dihedral angles of 80.20 (10)° with the furan ring, of 75.55 (10)° with the pyrrolidine ring, of 12.26 (10)° with the meth-oxy-phenyl ring and of 73.77 (13)° with the phenyl ring. The O atom attached to the β-lactam ring deviates by 0.0385 (13) Å from the ring plane. The mol-ecular conformation is stabilize  ...[more]

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