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(8-Benzoyl-2,7-dimeth-oxy-naphthalen-1-yl)(4-phen-oxy-phen-yl)methanone.


ABSTRACT: In the mol-ecule of the title compound, C32H24O5, the benzoyl group and the 4-phenoxy substituted benzoyl group at the 1- and 8-positions of the naphthalene ring system are aligned almost anti-parallel. The two benzene rings make a dihedral angle of 21.18?(10)°, and are inclined to the naphthalene ring system by 86.53?(9) and 82.95?(8)°, respectively. In the crystal, C-H?O inter-actions are observed involving aromatic and meth-oxy H atoms with ketonic carbonyl O atoms, as well as C-H?? inter-actions between aromatic H atoms and the ?-systems of naphthalene and benzene rings. These interactions form a three-dimensional architecture and afford a waved alignment of the naphthalene ring systems along the c axis.

SUBMITTER: Sasagawa K 

PROVIDER: S-EPMC3588546 | biostudies-literature | 2013 Mar

REPOSITORIES: biostudies-literature

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(8-Benzoyl-2,7-dimeth-oxy-naphthalen-1-yl)(4-phen-oxy-phen-yl)methanone.

Sasagawa Kosuke K   Sakamoto Rei R   Takeuchi Ryo R   Yonezawa Noriyuki N   Okamoto Akiko A  

Acta crystallographica. Section E, Structure reports online 20130220 Pt 3


In the mol-ecule of the title compound, C32H24O5, the benzoyl group and the 4-phenoxy substituted benzoyl group at the 1- and 8-positions of the naphthalene ring system are aligned almost anti-parallel. The two benzene rings make a dihedral angle of 21.18 (10)°, and are inclined to the naphthalene ring system by 86.53 (9) and 82.95 (8)°, respectively. In the crystal, C-H⋯O inter-actions are observed involving aromatic and meth-oxy H atoms with ketonic carbonyl O atoms, as well as C-H⋯π inter-act  ...[more]

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