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Di-?-hydroxido-bis-[dimeth-yl(thio-cyanato-?N)tin(IV)].

ABSTRACT: The Sn(IV) atom in the centrosymmetric title complex, [Sn2(CH3)4(NCS)2(OH)2], adopts a distorted trigonal-bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thio-cyanate anion are in the apical >positions. The dinuclear species are linked through O-H?S and C-H? S hydrogen-bonding inter-actions into a three-dimensional network.

SUBMITTER: Sow Y

PROVIDER: S-EPMC3588706 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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Di-μ-hydroxido-bis-[dimeth-yl(thio-cyanato-κN)tin(IV)].

Sow Yaya Y Diop Libasse L Molloy Kieran C KC Kociok-Köhn Gabriele G

Acta crystallographica. Section E, Structure reports online 20121103 Pt 12

The Sn(IV) atom in the centrosymmetric title complex, [Sn2(CH3)4(NCS)2(OH)2], adopts a distorted trigonal-bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thio-cyanate anion are in the apical >positions. The dinuclear species are linked through O-H⋯S and C-H⋯ S hydrogen-bonding inter-actions into a three-dimensional network. ...[more]

PMID: 23468671

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