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ABSTRACT:
SUBMITTER: Davis WL
PROVIDER: S-EPMC3588757 | biostudies-literature | 2012 Dec
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20121124 Pt 12
The title compound, [PdCl2(C21H12F9P)2]·CH2Cl2, crystallizes with two independent complex molecules (each having the Pd(II) atom situated on an inversion centre) and a dichloro-methane molecule in the asymmetric unit. The independent Pd(II) atoms are in perfectly linear orientations of the ligands in mutually trans positions, but distortions of the Cl-Pd-P angles ranging from 86.151 (19) to 93.849 (19)° are evident. The effective cone angles for the tris-[4-(trifluoro-meth-yl)phen-yl]phosphane l ...[more]