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Dimethyl-bis-(2-methyl-quinolin-8-olato-?(2) N,O)tin(IV).

ABSTRACT: The Sn(IV) cation in the title compound, [Sn(CH3)2(C10H8NO)2], is N,O-chelated by two 2-methyl-quinolin-8-olate anions and coordinated by two methyl groups in a skew-trapezoidal bipyramidal geometry. In the mol-ecule, the two quinoline ring systems are twisted to one another at 10.91?(18)°. The dimethyl-tin skeleton [C-Sn-C = 149.6?(2)°] is bent over the longer edge of the trapezoid that is defined by the four chelating atoms. Weak inter-molecular C-H?O hydrogen bonding occurs in the crystal.

SUBMITTER: Najafi E 

PROVIDER: S-EPMC3588791 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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Dimethyl-bis-(2-methyl-quinolin-8-olato-κ(2) N,O)tin(IV).

Najafi Ezzatollah E   Amini Mostafa M MM   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20121128 Pt 12

The Sn(IV) cation in the title compound, [Sn(CH3)2(C10H8NO)2], is N,O-chelated by two 2-methyl-quinolin-8-olate anions and coordinated by two methyl groups in a skew-trapezoidal bipyramidal geometry. In the mol-ecule, the two quinoline ring systems are twisted to one another at 10.91 (18)°. The dimethyl-tin skeleton [C-Sn-C = 149.6 (2)°] is bent over the longer edge of the trapezoid that is defined by the four chelating atoms. Weak inter-molecular C-H⋯O hydrogen bonding occurs in the crystal. ...[more]

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