Ontology highlight
ABSTRACT:
SUBMITTER: Kuroda DG
PROVIDER: S-EPMC3594387 | biostudies-literature | 2013 Apr
REPOSITORIES: biostudies-literature
Kuroda Daniel G DG Singh Prabhat K PK Hochstrasser Robin M RM
The journal of physical chemistry. B 20120925 16
The degenerate transition corresponding to asymmetric stretches of the D(3h) tricyanomethanide anion, C(CN)(3)(-), in aqueous solution was investigated by linear FTIR spectroscopy, femtosecond pump–probe spectroscopy, and 2D IR spectroscopy. Time resolved vibrational spectroscopy shows that water induces vibrational energy transfer between the degenerate asymmetric stretch modes of tricyanomethanide. The frequency–frequency correlation function and the vibrational energy transfer show two signif ...[more]