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?-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes.


ABSTRACT: Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford ?-dioxaborato amides and esters in high enantiomeric purity (90-95% ee).

SUBMITTER: Smith SM 

PROVIDER: S-EPMC3601746 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes.

Smith Sean M SM   Hoang Gia L GL   Pal Rhitankar R   Bani Khaled Mohammad O MO   Pelter Liberty S W LS   Zeng Xiao Cheng XC   Takacs James M JM  

Chemical communications (Cambridge, England) 20121201 100


Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90-95% ee). ...[more]

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