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Ultrathin optically transparent carbon electrodes produced from layers of adsorbed proteins.


ABSTRACT: This work describes a simple, versatile, and inexpensive procedure to prepare optically transparent carbon electrodes, using proteins as precursors. Upon adsorption, the protein-coated substrates were pyrolyzed under reductive conditions (5% H2) to form ultrathin, conductive electrodes. Because proteins spontaneously adsorb to interfaces forming uniform layers, the proposed method does not require a precise control of the preparation conditions, specialized instrumentation, or expensive precursors. The resulting electrodes were characterized by a combination of electrochemical, optical, and spectroscopic means. As a proof-of-concept, the optically transparent electrodes were also used as substrate for the development of an electrochemical glucose biosensor. The proposed films represent a convenient alternative to more sophisticated, and less available, carbon-based nanomaterials. Furthermore, these films could be formed on a variety of substrates, without classical limitations of size or shape.

SUBMITTER: Alharthi SA 

PROVIDER: S-EPMC3601777 | biostudies-literature | 2013 Mar

REPOSITORIES: biostudies-literature

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Ultrathin optically transparent carbon electrodes produced from layers of adsorbed proteins.

Alharthi Sarah A SA   Benavidez Tomás E TE   Garcia Carlos D CD  

Langmuir : the ACS journal of surfaces and colloids 20130304 10


This work describes a simple, versatile, and inexpensive procedure to prepare optically transparent carbon electrodes, using proteins as precursors. Upon adsorption, the protein-coated substrates were pyrolyzed under reductive conditions (5% H2) to form ultrathin, conductive electrodes. Because proteins spontaneously adsorb to interfaces forming uniform layers, the proposed method does not require a precise control of the preparation conditions, specialized instrumentation, or expensive precurso  ...[more]

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