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Bis{1-[(1H-benzimidazol-1-yl)meth-yl]-1H-imidazole-?N (3)}bis-(3,5-dicarb-oxy-benzoato-?(2) O (1),O (1'))nickel(II) octa-hydrate.

ABSTRACT: In the title complex, [Ni(C9H5O6)2(C11H10N4)2]·8H2O, the Ni(II) ion exhibits site symmetry 2. It has a distorted octa-hedral coordination defined by two N atoms from two symmetry-related 1-[(1H-benzimidazol-1-yl)meth-yl]-1H-imidazole ligands and four O atoms from two symmetry-related 3,5-dicarb-oxy-benzoate anions. In the crystal, the complex mol-ecules and solvent water mol-ecules are linked via O-H?O, O-H?N and N-H?O hydrogen bonds, forming a three-dimensional structure. There are also a number of C-H?O inter-actions present.

SUBMITTER: Jia YY

PROVIDER: S-EPMC3629470 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

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Bis{1-[(1H-benzimidazol-1-yl)meth-yl]-1H-imidazole-κN (3)}bis-(3,5-dicarb-oxy-benzoato-κ(2) O (1),O (1'))nickel(II) octa-hydrate.

Jia Yong-Yan YY Fan Jing-Jing JJ Yin Xiang-Ge XG Zhao Wen-Long WL

Acta crystallographica. Section E, Structure reports online 20130302 Pt 4

In the title complex, [Ni(C9H5O6)2(C11H10N4)2]·8H2O, the Ni(II) ion exhibits site symmetry 2. It has a distorted octa-hedral coordination defined by two N atoms from two symmetry-related 1-[(1H-benzimidazol-1-yl)meth-yl]-1H-imidazole ligands and four O atoms from two symmetry-related 3,5-dicarb-oxy-benzoate anions. In the crystal, the complex mol-ecules and solvent water mol-ecules are linked via O-H⋯O, O-H⋯N and N-H⋯O hydrogen bonds, forming a three-dimensional structure. There are also a numbe ...[more]

PMID: 23633988

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