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Dichloridobis(1,3-diisopropyl-4,5-di-methyl-1H-imidazol-3-ium-2-thiol-ate-?S)copper(II).

ABSTRACT: The mol-ecular structure of the title compound, [CuCl2(C11H20N2S)2], shows the Cu(II) atom with a distorted tetra-hedral geometry from two Cl atoms [Cu-Cl = 2.2182?(6)?Å] and two thione S atoms [Cu-S = 2.3199?(6)?Å]. The angles at the copper cation, which lies on a twofold rotation axis, are Cl-Cu-Cl = 142.84?(4)°, Cl-Cu-S = 94.80?(2) and 99.97?(2)°, and S-Cu-S = 132.46?(4)°. The planes of the two imidazolium rings make a dihedral angle of 76.92?(8)°.

SUBMITTER: Florke U

PROVIDER: S-EPMC3629488 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

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Dichloridobis(1,3-diisopropyl-4,5-di-methyl-1H-imidazol-3-ium-2-thiol-ate-κS)copper(II).

Flörke Ulrich U Ahmida Aziza A Schröder Jörg J Egold Hans H Henkel Gerald G

Acta crystallographica. Section E, Structure reports online 20130316 Pt 4

The mol-ecular structure of the title compound, [CuCl2(C11H20N2S)2], shows the Cu(II) atom with a distorted tetra-hedral geometry from two Cl atoms [Cu-Cl = 2.2182 (6) Å] and two thione S atoms [Cu-S = 2.3199 (6) Å]. The angles at the copper cation, which lies on a twofold rotation axis, are Cl-Cu-Cl = 142.84 (4)°, Cl-Cu-S = 94.80 (2) and 99.97 (2)°, and S-Cu-S = 132.46 (4)°. The planes of the two imidazolium rings make a dihedral angle of 76.92 (8)°. ...[more]

PMID: 23634006

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